For me I have seen much better usage of memory with Windows Server 2008 over Server 2003. Depending on your hardware specs you might be able to get around having to have Ent Ed of Windows. The disk partition alignment @KenJ mentioned is huge for SQL Server. I was very excited to hear that was taken care of in Server 2008. Running on an Operating System that is current is a plus by itself.
Could I suggest that if you take the step, go for 2008 R2. There aren't many differences, but stuff like Powershell have been improved upon and the clustering too, if that were to come up in the future. The network improvements that @meltondba talks about *really* do work!